ICAMS / Interdisciplinary Centre for Advanced Materials Simulation


Tumbling of polymers in semidilute solution under shear flow

C.C. Huang, R.G. Winkler, G. Sutmann, G. Gompper.

European Physics Letters, 93, 54004, (2011)

The tumbling dynamics of individual polymers in semidilute solution is studied by large-scale non-equilibrium mesoscale hydrodynamic simulations. We find that the tumbling time is equal to the non-equilibrium relaxation time of the polymer end-to-end distance along the flow direction and strongly depends on concentration. In addition, the normalized tumbling frequency as well as the widths of the alignment distribution functions for a given concentration-dependent Weissenberg number exhibit a weak concentration dependence in the cross-over regime from a dilute to a semidilute solution. For semidilute solutions a universal behavior is obtained. This is a consequence of screening of hydrodynamic interactions at polymer concentrations exceeding the overlap concentration.

DOI: 10.1209/0295-5075/93/54004
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