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Thermochemical properties of MeCuO2 and Me2CuO3 (Me = Ca, Sr, Ba) mixed oxides
Optimized experimental data and estimated values are utilized for the assessment of thermochemical functions of alkali-earth cuprates. For the determination of temperature dependences of heat capacities the Neumann-Kopp additive rule was employed, Values of standard enthalpy of formation and molar entropy of Ca2CuO3, SrCuO2 , Sr2 CuO3 and BaCuO2 were optimized from experimental results. For the estimation of enthalpies of formation of CaCuO2 and Ba2CuO3 a linear correlation between enthalpy of formation from oxides and ionic radius of alkali-earth cations was used. Molar entropy of CaCuO2 and Ba2 CuO3 was estimated using the modified contribution method.