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Emergence of superconductivity in doped H2O ice at high pressure

J. Flores-Livas, A. Sanna, M. Graužinytė, A. Davydov, S. Goedecker, M. Marques

Scientific Reports, 7, 6825, (2017)

DOI: 10.1038/s41598-017-07145-4

Download: BibTEX

We investigate the possibility of achieving high-temperature superconductivity in hydrides under pressure by inducing metallization of otherwise insulating phases through doping, a path previously used to render standard semiconductors superconducting at ambient pressure. Following this idea, we study H2O, one of the most abundant and well-studied substances, we identify nitrogen as the most likely and promising substitution/dopant. We show that for realistic levels of doping of a few percent, the phase X of ice becomes superconducting with a critical temperature of about 60 K at 150 GPa. In view of the vast number of hydrides that are strongly covalent bonded, but that remain insulating up to rather large pressures, our results open a series of new possibilities in the quest for novel high-temperature superconductors.

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{"type":"article", "name":"j.flores-livas20177", "author":"J. Flores-Livas and A. Sanna and M. Graužinytė and A. Davydov and S. Goedecker and M. Marques", "title":"Emergence of superconductivity in doped H2O ice at high pressure", "journal":"Scientific Reports", "volume":"7", "OPTnumber":"1", "OPTmonth":"7", "year":"2017", "OPTpages":"6825", "OPTnote":"", "OPTkey":"", "DOI":"10.1038/s41598-017-07145-4"}
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