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Water’s phase diagram remains one of the most intricate and challenging benchmarks in molecular modeling. In this study, we compute the phase diagram of water using an Atomic Cluster Expansion (ACE) potential previously developed by us and trained on density-functional theory (DFT) calculations based on the revPBE-D3 exchange–correlation functional. We compute solid–liquid chemical potential differences and melting points using biased coexistence simulations with the On-the-Fly Probability Enhanced Sampling (OPES) method. Starting from these points, we trace coexistence lines using Gibbs–Duhem integration. This combination of methods allows us to consistently map pressure–temperature phase boundaries and reconstruct the full phase diagram between approximately 100–500 K and 0–4 GPa. The stability regions of the main ice polymorphs (Ih, II, V, VI, and VII) are reproduced in close agreement with experiments. As in earlier studies based on DFT, ice III is metastable, and there are systematic shifts of coexistence lines with respect to experimental results. Our results demonstrate the capability of our general-purpose ACE potential to capture the complex phase behavior of water across a wide range of thermodynamic conditions.