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Influence of hydrogen-bonding on the reduction potential of a Cu(II) center

T. Glaser, I. Liratzis, O. Kataeva, R. Fröhlich, M. Piacenza, S. Grimme

Chem. Comm., 9, 1024-1026, (2006)

DOI: 10.1039/b517340j

Download: BibTEX

Two hydrogen-bonds from geometrically constrained OH groups to coordinated oxygen donors shift the reduction potential of a Cu-II complex by + 270 mV as compared to the structurally analogous reference complex missing the OH groups.

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